Texas A&M University College Station - Mechanical Engineering
PhD
PhD Dissertation Title: Mechanical Behavior and Environmental Stability of GLAD-based Copper Nanospring Films for Nanothermal Interfaces\nAdvisor: Prof. Ioannis Chasiotis\nGPA: 3.86/4.00
Aerospace Engineering (Materials and Structures)
Philosophical Society of Turkey
Society for Experimental Mechanics (SEM)
Society for Industrial and Applied Mathematics
Society for the Advancement of Material and Process Engineering
American Society for Composites
Materials Research Society
University of Illinois at Urbana-Champaign
All research safety and experimental facility supervision certificates of the Texas A&M System
TAMU College Station
M.S.
M.Sc. Thesis Title: Mechanical and Interfacial Properties of Carbon Nanofibers for Polymer Nanocomposites\nGPA: 4.00/4.00
Mechanical Engineering
GEO
Federation of Teachers Illinois Branch
Landesverwaltung der Amischen Gemeinde in den Vereinigten Staaten für landwirtschaftliche Entwicklung
University of Illinois at Urbana-Champaign
BS
B.Sc. Thesis Title: Improvement of Process Yield and Octane Rating for Biodiesel Synthesis by Mechanical and Acoustic Means \nGPA: 3.79/4.00
Mechanical Engineering
Founding member of Solar Car & SAE Mini Baja Teams
Member of the Environmental Safeguarding Club
Founding member of the Eastern Thrace Biodiesel Initiative (биодизел инициатива по Тракия)
Bosphorus University
Students demonstrate 3D printing technology's potential value for society on the 25th anniversary of ADA | 22 | 07 | 2015 | News & Events | College of Engineering
A team of students from the Department of Mechanical Engineering at Texas A&M University recently showcased its 3D printing skills by printing braille labels on prescription bottles. The team is led by Dr. Tanil Ozkan
who is a visiting assistant professor in the department.
Students demonstrate 3D printing technology's potential value for society on the 25th anniversary of ADA | 22 | 07 | 2015 | News & Events | College of Engineering
Texas A&M's 3D Braille Printer Can Print on Any Curved or Flat Plastic Surface
As technology improves
so do the lives of those individuals living with disabilities all around the world. 3D printing has become one of those technologies aiding in creating custom devices
prostheses
and more for individuals who previously would have been left with fewer reliable options.
Texas A&M's 3D Braille Printer Can Print on Any Curved or Flat Plastic Surface
Nanoparticle/Microwave Interactions
Simulations
Mathematical Modeling
Nanofabrication
Finite Element Analysis
Characterization
Nanocomposites
Composites
MEMS
Process Engineering
Materials Development
CVD
Functionally Graded Materials
Solid Mechanics
Fracture Mechanics
Structures
Nanotechnology
AFM
Experimental Research
Nanomaterials
Interfacial strength and fracture energy of individual carbon nanofibers in epoxy matrix as a function of surface conditions
Ioannis Chasiotis
The interfacial shear strength (IFSS) and fracture energy of individual carbon nanofibers embedded in epoxy were obtained for different surface conditions and treatments by novel
MEMS-based
nanoscale fiber pull-out experiments. As-grown vapor grown carbon nanofibers (VGCNFs) with turbostratic surface and 5 nm peak-to-valley surface roughness exhibited high IFSS and interfacial fracture energy
averaging 106 ± 29 MPa and 1.9 ± 0.9 J/m^2
respectively. Subsequent high temperature heat treatment and graphitization resulted in drastically reduced IFSS of 66 ± 10 MPa and interfacial fracture energy of 0.65 ± 0.14 J/m^2. The smaller IFSS values and the reduced standard deviation were due to significant reduction of the fiber surface roughness to 1–2 nm
as well as a decrease in surface defect density during conversion of turbostratic and amorphous carbon to highly ordered graphitic carbon. For both grades of VGCNFs failure was adhesive with clear nanofiber surfaces after debonding. Oxidative functionalization of high temperature heat-treated VGCNFs resulted in much higher IFSS of 189 ± 15 MPa and interfacial fracture energy of 3.3 ± 1.0 J/m^2. The debond surfaces of functionalized nanofibers had signs of matrix residue and/or shearing of the outer graphitic layer of the VGCNFs
namely the failure mode was a combination of cohesive matrix and/or cohesive fiber failure which contributed to the high IFSS. For all three grades of VGCNFs the IFSS was independent of fiber length and diameter. The findings of this experimental study emphasized the critical role of nanofiber surface morphology and chemistry in determining the shear strength and fracture energy of nanofiber interfaces
and shed light to prior composite-level strength and fracture toughness measurements.
Interfacial strength and fracture energy of individual carbon nanofibers in epoxy matrix as a function of surface conditions
In this study
the aim is to configure the cutting operations made use of during the production of Hydroxilapatite (HAp) - a highly biocompatible ceramic used in orthopedics and dentistry as an implant and implant coating material - from cow femoral bone in such a way that maximum surface area is achieved. First
the cutting patterns which would yield the highest surface area when applied to a cow femur of known geometric properties have been investigated using a computer code prepared with the technical computing program
MATLAB 6.5. The obtained results have been compared with the results of cutting operations applied on a realistic 3-D bone model prepared using CATIA v5 modeling software.
Theoretical Maximization of Cow Femur Cut Surface Area for Hydroxilapatite Production
Ioannis Chasiotis
The complex effects of near ambient temperature exposure
i.e. 20-150 ºC
on the oxidation and the mechanical properties of thermal solution grown faceted Cu nanowires were investigated. The mechanical behaviour was quantified with experiments on individual Cu nanowires using a MEMS-based method for nanoscale mechanical property studies. The elastic modulus of pristine Cu nanowires with diameters 300-550 nm was 117±1.2 GPa which agreed very well with polycrystalline bulk Cu
while the ultimate tensile strength was more than three times higher than bulk Cu
averaging 683±55 MPa. Annealing at only 50˚C resulted in marked strengthening by almost 100% while the elastic modulus remained unchanged. Heat treatment in ambient air distinguished three different regimes of oxidation
namely the (a) formation of a thin passivation oxide at temperatures up to 50˚C
(b) formation of thermal oxide obeying an Arrhenius type process for Cu+ migration at temperatures higher than 70˚C
which was accelerated by grain boundary diffusion resulting in activation energies of 0.17-0.23 eV
and (c) complete oxidation following the Kirkendall effect at temperatures higher than 150 ˚C and for prolonged exposure times
which did not obey an Arrhenius law. Notably
the formation of a weaker and more compliant thermal Cu2O did not compromise the effective strength and elastic modulus of oxidized Cu nanowires: experiments in Ar at temperatures higher than 70ºC showed mechanical strengthening by ~50% and ultimate stiffening to ~190 GPa
which is near the upper limit for the elastic modulus of single crystal Cu in the <111> direction.
Mechanical strengthening
stiffening
and oxidation behaviour of pentatwinned Cu nanowires at near ambient temperatures
John R. Abelson
Thin films of HfBxCy are deposited in a cold wall CVD apparatus using Hf(BH4)4 precursor and\n3
3-Dimethyl-1-butene
(CH3)3CCH=CH2
as a controllable source of carbon
at substrate\ntemperatures of 250-600°C. As-deposited films grown at 250°C are highly conformal in trenches\nwith aspect ratios of at least 30:1
exhibit dense microstructure
and appear amorphous in X-ray\ndiffraction. Increasing the carbon content from 5 to 21 at. % decreases the hardness from 21 to 9\nGPa and the elastic modulus from 207 to 114 GPa. Films grown at 600°C with carbon contents\nof 28 and 35 at. % exhibit enhanced hardness of 25 and 23 GPa
and elastic modulus of 211 and\n202 GPa
respectively. Annealing the 300°C grown films at 700°C affords a nanocrystalline\nstructure with improved mechanical properties: the H/E and H3/E2 ratios range from 0.08-0.11\nand 0.15-0.40
respectively
which are predicted to exhibit improved friction and wear\nperformance in tribological applications.
Conformal growth of low friction HfBxCy hard coatings
Potentials of Augmented Reality (AR) and Virtual Reality (VR) for Mechanical Engineering Education at the Age of Personal 3D Printers
Arun Srinivasa
Troy Mitchell
All Fortune 500 companies dealing with some form of product design
development and manufacturing processes are implementing new strategies to adapt to the rapidly changing manufacturing landscape after the digital revolution in the last two decades of the 20th century. For the first time since the industrial revolution
engineers are observing a trend which is challenging all mass production based manufacturing paradigms. 3D printing and additive manufacturing sit at the very heart of this transition. The 2015 Higher Education Edition of the NMC Horizon Report has identified 3D printing as one of three technologies (the other two are big data/cloud computing and wearable tech) expected to enter mainstream use in the midterm horizon of three to five years. “One of the most significant aspects of 3D printing for education
” the report notes
“is that it enables more authentic exploration of objects that may not be readily available to universities.” Based on the AR/VR systems development experience in the 3D Printing Studio and MEEN 361 Materials and Manufacturing in Design Laboratory of the Department of Mechanical Engineering at Texas A&M University
classes discuss opportunities and challenges presented by these emerging technologies for mechanical engineering education. From the holistic pedagogic perspective of integrating advanced technology driven learning objectives into existing curriculum of mid-years students
the Department of Mechanical Engineering at Texas A&M University is able to enhance the learning experience and innovation potential of students
making them more competitive in the job market and supplying them with indispensable skills for their professional careers after graduation.
Potentials of Augmented Reality (AR) and Virtual Reality (VR) for Mechanical Engineering Education at the Age of Personal 3D Printers
Ioannis Chasiotis
Mohammad Naraghi
Individual as-fabricated
high temperature heat-treated and graphitized/surface oxidized vapor grown carbon nanofibers (VGCNFs)
with average diameter of 150 nm were tested for their elastic modulus and their tensile strength by a MEMS-based mechanical testing platform. The elastic modulus increased from 180 GPa for as-fabricated
to 245 GPa for high temperature heat-treated nanofibers. The nominal fiber strengths followed Weibull distributions with characteristic strengths between 2.74 and 3.34 GPa
which correlated well with the expected effects of heat treatment and oxidative post-processing. As-fabricated VGCNFs had small Weibull modulus indicating a broad flaw population
which was condensed upon heat treatment. For all VGCNF grades
the nanofiber fracture surface included the stacked truncated cup structure of the oblique graphene layers comprising its backbone and cleavage of the outer turbostratic or thermally graphitized layer.
Mechanical Properties of Vapor Grown Carbon Nanofibers
Ioannis Chasiotis
A novel experimental method for the interfacial mechanics of nanofibers and nanotubes was developed. The debond force was determined by MEMS devices whose motion was precisely measured from optical images by digital image correlation. Essential elements of this method are the submicron control of nanofiber/nanotube embedded length in a thermoplastic or thermosetting polymer and the application of well controlled pull-out force until terminal debonding. The cross-head displacement resolution is at least 20 nm whereas a force resolution of the order of nanonewtons is maintained. A traceable force calibration technique was integrated to calibrate the MEMS force sensors. The method allows for nanofiber pull-out experiments at time scales varying from microseconds to hours and at hot/cold temperatures. Experiments have been conducted for the first time with ø150-350 nm carbon nanofibers embedded in EPON epoxy to demonstrate the applicability of the proposed method. The present experiments are the first of their kind both in terms of experimental fidelity and data coherence compared to prior experimental attempts
pointing out to the robustness of this new method.
Standardization of nanoscale interfacial experiments using MEMS
Kathleen A. Walsh
Density modulated tungsten (W) thin film samples whose nanoscale porosity contents ranged\nfrom 7% to 40% by volume were grown on Si substrates through magnetron sputter deposition.\nProcess parameters for the film growth were selected according to the structure zone model\n(SZM)
which resulted in film thicknesses between 105 nm and 520 nm. Nanomechanical\nproperties of W films were investigated by means of instrumented nanoindentation. Reduced\nchi-square analysis was carried out to assess four different models formulated through differential effective medium approach (DEMA). The model that factored in both the crowding effect and the maximum random packing of pores
successfully captured the experimental trends present in the reduced modulus data as a function of porosity. Attempts to breach the auxetic barrier by increasing the porosity content beyond the level predicted by the model with the highest fidelity resulted in either large-scale pulverization during deposition or spontaneous conversion of the deposited film into WO3 under ambient conditions. Porosity corrected yield strength calculations revealed that it is indeed possible to define a porosity threshold beyond which the compressive yield strength of density modulated metallic thin films would drop abruptly due to aggravated geometric slenderness effects in agreement with earlier hypotheses.
Density modulated nanoporous tungsten thin films and their nanomechanical properties
Silicon (Si) electrodes possess a theoretical specific capacity nearly ten times that of current graphite electrodes used in lithium ion batteries. However
lithiation and delithiation induce large volume changes within the Si
resulting in cracking and eventual capacity loss with cycling. Recent experimental evidence indicates that the presence of nanoporosity may mitigate capacity fade. By implementing a scalable differential effective medium approach
we elucidate the effects of nanoporosity upon the mechanical properties of fully-lithiated amorpohous Si anode films. Our analytical findings suggest that increased pore volume fraction significantly alters the mechanical properties of nanofilms and enhances anode survivability. Meanwhile
the auxetic limit imposes an upper bound on porosity specific fracture toughening. Overall
the results of this paper provide design guidelines for multilayered nanoporous Si thin films with increased capacity retention.
Mechanical Properties of Nanoporous Si Anodes using a Continuum Mechanical Model
Maarten P. de Boer
Sidhart S. Hazra
Ioannis Chasiotis
Mohammad Naraghi (1st author)
A new nanoscale tension testing platform with on-chip actuation and the unique capability for nanoscale mechanical characterization of highly deformable and strong nanostructures is presented. The specimen force and extension measurements are based on optical imaging
supported by digital image correlation
which allows the resolution of 20 nm specimen extensions and force measurements better than 30 nN
without the use of high-resolution electron microscopy. The breakthrough of this nanomechanical testing platform is the ability to study the mechanical behavior of nanostructures subjected to a wide range of forces (30 nN–300 μN) and displacements (20 nm–100 μm)
which are beyond the limits of typical surface micromachined MEMS with on-chip actuators
such as comb-drives and thermal actuators. The utility of this device in experimental nanomechanics is demonstrated by investigating the mechanical behavior of electrospun 1-D polyacrylonitrile nanostructures with diameters of 200–700 nm subjected to strains as high as 200%. The mechanical property measurements were compared to and agreed well with off-chip measurements by an independent testing method
which validates the capability of this on-chip testing platform to characterize strong and highly ductile nanomaterials.
MEMS platform for on-chip nanomechanical experiments with strong and highly ductile nanofibers
Driven by both the implications of the recent disaster in Fukushima as well as the coming maturity of fusion reactors in energy infrastructure
the nuclear industry is experiencing a renaissance not only in reactor design and fuel systems but also in safety. However
the combination of high temperature
high pressure
and radiation intensityof a reactor core poses a challenge to material selection for engineers
particularly related to nuclear cladding. Creep and cracking pose a threat to the cladding’s functional integrity. As a result
high fracture toughness
low thermal expansion coefficient
and wear resistance become crucial metrics for the design and selection of nuclear cladding material for control rods. In response to these metrics
boron carbide (B4C) and Ag–In–Cd alloy have emerged as promising candidates for usage in control rod claddings. However
nanoporosity can impart significant mechanical advantages including higher fracture toughness
increased defect annihilation
and suppressed irradiation swelling. Density-modulated tungsten thin films with tunable nanoporosity can be manufactured through sputter coating. Consequently
density-modulated tungsten thin films have the potential to contribute to next-generation control rod cladding. Thus
the objective of this paper is to investigate the suitability of density-modulated tungsten thin films for nuclear control rod cladding through the analytical hierarchy process. Overall
conservative analytical hierarchy process analysis indicates that nanoporous tungsten is competitive with B4C for control rod cladding. As a result
our study may motivate current and future control rod cladding material development efforts focusing specifically on hybrid density-modulated tungsten thin film and B4C architectures for next-generation nuclear power plants.
Nanoporous Tungsten for Improved Mechanical Performance and Safety in Nuclear Control Rod Cladding
Three grades of VGCNFs
namely as-fabricated
high temperature heat treated
and graphitized/surface oxidized
with average diameters of 150 nm were tested individually for their tensile strength by a MEMS mechanical testing platform. Their nominal tensile strengths followed Weibull distributions with characteristic strength values between 2.74- 3.34 GPa
which correlated well with the expected effects of heat treatment and oxidative post-processing. These values are the first measurements reported for VGCNFs and are more than 50% smaller than the generally accepted values for the tensile strength of this class of nanofibers. The as-fabricated nanofibers had the smallest Weibull modulus indicating a wide flaw population that was reduced significantly upon heat treatment. Under uniaxial tension
cleavage of the outer turbostratic layer occurred first
followed by relative slip of the internal oblique graphene layers. The change in the mechanical strength (Weibull strength)
and its scatter (Weibull moduli)
with heat treatment correlated well with the fiber structure evidence in Transmission Electron Microscopy (TEM) images
which showed graphitization of the outer turbostratic layer and the formation of a new interface with the inner
originally graphitic
layer that was characterized by structural discontinuities that reduced the total load bearing capacity of the nanofibers. In this work
the strength of the carbon nanofiber-polymer matrix interfaces was also quantified for the frrst time by means of novel nanoscale fiber pull-out experiments. The interfacial shear strength averaged 55 MPa revealing that the adhesion and bonding of the heat-treated
non-functionalized carbon nanofibers is quite better than that of non-functionalized carbon fibers (15-28 MPa) and as good as that of functionalized carbon fibers ( 40-65 MPa)
which underscores that extrapolations of macroscale interfacial measurements to the nanoscale are not appropriate.
Ioannis Chasiotis
Tanil
Ozkan
Texas A&M University
Dover Precision Components
Ford Motor Company
The Nanomechanics and Materials Research Laboratory (NMRL) of UIUC
DuPont
University of Illinois at Urbana-Champaign LINC
Texas A&M University Department of Mechanical Engineering & NCTM
Houston
Texas Area
At the Engineering Polymers Innovation Center (EPIC) of Dover Precision Components in Pearland
TX
we are pushing the limits of high performance engineering polymers and their nanocomposites to ensure optimum efficiency
reliability
productivity and environmental stewardship in even the most challenging operating environments across the oil & gas
power generation
marine
industrial
chemical and general processing markets. Our team led by Dr. Burak Bekisli is committed to safety
quality
sustainability and continuous improvement in all that we do.
Materials Engineer and Additive Manufacturing Specialist
Dover Precision Components
Intern at the Engineering Polymers Division of \nDuPont de Nemours Intl. S.A. European Technical Centre \nRepublic and Canton of Geneva / Switzerland
DuPont
Research Assistant
Title of the doctor philosophiae (Ph.D.) dissertation: MECHANICAL BEHAVIOR AND ENVIRONMENTAL STABILITY OF GLAD-BASED COPPER NANOSPRING FILMS FOR NANOTHERMAL INTERFACES\nhttps://www.ideals.illinois.edu/handle/2142/49795\n\nTitle of the magister scientiae (M.Sc.) thesis: MECHANICAL AND INTERFACIAL PROPERTIES OF VAPOR GROWN CARBON NANOFIBERS FOR POLYMER NANOCOMPOSITES\nhttps://www.ideals.illinois.edu/handle/2142/47634
The Nanomechanics and Materials Research Laboratory (NMRL) of UIUC
University of Illinois at Urbana-Champaign LINC
UIUC College of Engineering
http://linc.illinois.edu/electric-vehicle-initiative
Electric Vehicle Initiative Project Manager
Intern at the Production Maintenance Division of Ford/Otosan Turkey.\nGolcuk Commercial Vehicle Manufacturing Plant\nKocaeli - Republic of Turkey
Ford Motor Company
Texas A&M University Department of Mechanical Engineering & NCTM
Bryan/College Station
Texas Area
Teaching:\nMEEN 360 Materials and Manufacturing in Design\nMEEN 361 Materials and Manufacturing Laboratory (Instructor of Record)\nMEEN 402 Senior Design \nMEEN 404 Engineering Laboratory\nMEEN 467 Mechanical Behavior of Engineering Materials\nMEEN 475 Materials Selection in Design\nMEEN 485 Directed Studies: Carbon Nanofiber Functionalized Electroactive Polymer Composites \nMEEN 625 Mechanical Behavior of Advanced Materials\n\n\nTechnology Research:\nCollaboration with Polycarpou Research Group (Nanotribology and Functional Thin Film Technology)\nResearcher and System Developer at the MEEN 3D Printing Studio \nMember of the Texas A&M Energy Research Society\n\nDidactic Research:\nImplementation of Virtual Reality in Materials Testing Curriculum of Mechanical Engineering\nExperiential Learning Enhancement in Engineering Labs through Virtual Reality\nVirtual Reality as a Learning Tool for Decision Making in Materials Selection
Instructional Assistant Professor
Department of Mechanical Engineering
3D Printing Materials Innovation Lab
Teaching:\nMEEN 222 Introductory Materials Science\nMEEN 361 Materials and Manufacturing Laboratory (Instructor of Record)\nMEEN 489/689 Entrepreneurship Related to Nanomaterials for Energy Applications (Guest Lecturer for Technical Lectures)\nMEEN 489 Custom Manufacturing (with Dr. Bruce Tai
I focus on Additive Manufacturing and Direct Digital Manufacturing
i.e. DDM in this class)\n\nResearch:\nMember of the Polycarpou Research Group\nResearcher and System Developer at the 3D Printing Materials Innovation Laboratory (affiliated with the 3D Printing Studio of the Mechanical Engineering Department)\nMember of the Texas A&M Energy Research Society
Visiting Assistant Professor
Texas A&M University
Polycarpou Research Group
ENG\nFrom the general mechanics point of view
the true beauty and brilliancy of the existing order within the physical universe is the following: Although the holonic architecture keeps the fundamental laws for the entire spatio-temporal spectrum more or less the same
it also provides a certain degree of autonomy within each individual scale without sacrificing the overall compatibility such that formation of a fragile system of absolute hierarchy is wisely avoided. Inspired by this very principle
here at the Polycarpou Research Group of Texas A&M University
we employ state of the art experimental techniques and pure human reasoning to unravel mechanical mysteries of novel nanostructured materials and thus identify key engineering concepts of the nanoscale with particular emphasis on multifunctional
tribological and 3D printing oriented applications. \n\nGER\nIn der Natur ist alles nach Maß
Zahl und Verhältniswert geordnet. Durch unsere Experimente in der Polycarpou Forschungsgruppe versuchen wir einige grundlegende Prinzipien dieser Ordnung sowie unter besonderen Bedingungen auftretende mechanische und tribologische Eigenschaften für neue Materialien und multifunktionale Bauelemente von verschiedenen Spitzentechnologien auf der Nanometer-Skala zu erklären.
Postdoctoral Research Associate
Texas A&M University
American Society for Engineering Education
Turkish
Arabic
German
English
Top 5 Entry in the Consumer Products Category of the Create the Future 2015 Design Contest with the '3D Printer to Aid Visually Impaired Consumers in Their Daily Life'
The Certificate of Achievement presented to Tanil Ozkan on behalf of Texas A&M 3D Braille Printeers Team (Yasushi Mizuno
Eduardo Vasquez and Bryan Conlee) recognizing the submission '3D Printer to Aid Visually Impaired Consumers in Their Daily Life' as a Top 100 Entry in the general contest and as a Top 5 Entry in the consumer products category.
Joseph T. Pramberger
President
Tech Briefs Media Group
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