Resume

• 2005

  Russian

  German

  English

  French

  Doctor of Philosophy (PhD)

  Thesis title: Sulfenates in AdE reactions\nSupervisor: \nHead of Laboratory of Biologically Active Compounds

  Professor

  Doctor of Science

  Nikolai V. Zyk; \nSenior researcher

  PhD

  Anna Yu. Gavrilova\nSpecialization: Organic Chemistry

  Chemistry of Hetero-organic compounds\nAttended courses: Advanced organic synthesis (Molecular orbitals in organic chemistry

  Computational modeling in organic chemistry

  Asymmetric synthesis

  Modern methods of physico-chemical analysis); Philosophy of modern science\nResponsibilities included supervision of 2 graduate projects and 5 course papers

  Organic Chemistry

  Lomonosov Moscow State University (MSU)

• 2000

  BS/MS

  organic chemistry

  Московский Государственный Университет им. М.В. Ломоносова (МГУ) / Lomonosov Moscow State University (MSU)

  GPA 3.98 of 4.00

• 290

  Greg Metzel

  Roman Ezhov

  J. Photochem. Photobiol. A.

  101-108

  Photoactive spatial proximity probes for binding pairs with epigenetic marks

  Intramolecular Cycloadditions of Photogenerated Azaxylylenes: An Experimental and Theoretical Study

  Andrei G. Kutateladze

  Anunay Samanta

  M Chandra Sekhar

  Cole Cronk

  Intramolecular Cycloadditions of Photogenerated Azaxylylenes: An Experimental and Theoretical Study

  Photoassisted Diversity-Oriented Synthesis: Accessing 2

  6-Epoxyazocane (Oxamorphan) Cores

  Andrei G. Kutateladze

  Teresa Cowger

  Photoassisted Diversity-Oriented Synthesis: Accessing 2

  6-Epoxyazocane (Oxamorphan) Cores

  Conformationally Constrained Penta(hetero)cyclic Molecular Architectures via Photoassisted Diversity-Oriented Synthesis.

  Andrei G. Kutateladze

  Conformationally Constrained Penta(hetero)cyclic Molecular Architectures via Photoassisted Diversity-Oriented Synthesis.

  Lewis acids as co-reagents in sulfenylation reactions

  Nikolay S. Zefirov

  Oxana B. Bondarenko

• 82

  Maxim Nechaev

  Anna Yu. Gavrilova

  Nikolay V. Zyk

  Russian Journal of General Chemistry

  1819-1821

  Aminosulfenates in the electrophilic addition reactions

  Photoinduced \"Double Click\" Cascade Offers Access to Complex Polyheterocycles from Readily Available Isatin-Based Photoprecursors

  Andrei G. Kutateladze

  W. Cole Cronk

  Photoinduced \"Double Click\" Cascade Offers Access to Complex Polyheterocycles from Readily Available Isatin-Based Photoprecursors

  Photoassisted access to Complex Polyheterocycles Containing a β-lactam moiety.

  Andrei G. Kutateladze

  Photoassisted access to Complex Polyheterocycles Containing a β-lactam moiety.

  Photoassisted Access to Enantiopure Conformationally Locked Ribofuranosylamines Spiro-Linked to Oxa

  zolidino- Diketopiperazines

  Andrei Kutateladze

  Photoassisted Access to Enantiopure Conformationally Locked Ribofuranosylamines Spiro-Linked to Oxa

  zolidino- Diketopiperazines

  Photoinduced Cycloadditions in the Diversity-Oriented Synthesis Toolbox: Increasing Complexity with Straightforward Postphotochemical Modifications

  Andrei G. Kutateladze

  Photoinduced Cycloadditions in the Diversity-Oriented Synthesis Toolbox: Increasing Complexity with Straightforward Postphotochemical Modifications

  Mukhina

  Moscow State University

  University of Denver

  Amgen

  Massachusetts Institute of Technology (MIT)

  •\tDeveloped new methods of AdE reactions of sulfenates and sulfenamides\n

  Moscow State University

  teaching assistant

  Moscow State University

  University of Denver

  Denver

  Colorado

  •\tDeveloped a new photoassisted approach to give conformationally constrained N

  O

  S-polyheterocyclic scaffolds of unprecedented topologies\n•\tExpanded the scope of the reaction by introduction of o-amido imines and oxazolines into the photochemical reactions with the possibility of enantioselective transformations in such systems\n•\tProposed a mechanism for intramolecular cycloadditions of azaxylylenes photogenerated via excited-state intramolecular proton transfer (ESIPT) in aromatic o-amido ketones and aldehydes \n\n\n

  Postdoctoral Research Fellow

  Prof. Kutateladze lab

  Cambridge

  Massachusetts

  Scientist

  Amgen

  Denver

  Colorado

  •\tDeveloped a new photoassisted approach to give conformationally constrained N

  O

  S-polyheterocyclic scaffolds of unprecedented topologies\n•\tExpanded the scope of the reaction by introduction of o-amido imines and oxazolines into the photochemical reactions with the possibility of enantioselective transformations in such systems\n•\tProposed a mechanism for intramolecular cycloadditions of azaxylylenes photogenerated via excited-state intramolecular proton transfer (ESIPT) in aromatic o-amido ketones and aldehydes \n•\tDiscovered a novel mode for dearomatization of electron rich heterocycles and carbocyclic arenes based on a formal [2+4] reaction with azaxylylenes

  arene acting as 2π component\n•\tDiversified the photoproducts library by application of postphotochemical reactions

  including hetero-Diels-Alder reaction

  [1

  3]-dipolar cycloaddition

  Suzuki coupling\n\n

  Associate Research Scientist

  Prof. Kutateladze lab

  University of Denver

  •\tDeveloped new methodologies for C-C bond formation via regio- and stereocontrolled diazene fragmentation\n•\tDeveloped novel strategies for C3a-functionalization of C3a-bromocyclotryptamines via electrophilic activation\n•\tApplied the novel methodologies towards the synthesis of natural products and analogues\n

  Massachusetts Institute of Technology (MIT)

• 80

  Andrei G. Kutateladze

  J. Org. Chem.

  5218-5225

  Minimalist Relativistic Force Field: Prediction of Proton-Proton Coupling Constants in 1H NMR Spectra is Perfected with NBO Hybridization Parameters.

  Photoassisted Synthesis of Complex Molecular Architectures: Dearomatization of Benzenoid Arenes with Aza-o-xylylenes via an Unprecedented [2+4] Reaction Topology.

  Photoassisted Synthesis of Complex Molecular Architectures: Dearomatization of Benzenoid Arenes with Aza-o-xylylenes via an Unprecedented [2+4] Reaction Topology.

  Cycloadditions of Azaxylylenes and Postphotochemical Capstone Modifications via Suzuki Coupling Procide Access to Complex Polyheterocyclic Biaryls

  Andrei G. Kutateladze

  Cole Cronk

  Cycloadditions of Azaxylylenes and Postphotochemical Capstone Modifications via Suzuki Coupling Procide Access to Complex Polyheterocyclic Biaryls

  Aminosulfenates in the electrophilic addition reactions

  Nikolay S. Zefirov

  Oxana B. Bondarenko

• 55

  Anna Yu. Gavrilova

  Nikolay V. Zyk

  Russ. Chem. Bull.

  1865-1866

  Halotrimethylsilanes as activating coreagents in sulfenylation reactions of olefins

  Azo-derivative of phenylboronic acid as an active component of the membrane reversible to salicilate-anion

  Natalia V. Shvedene

  Inna N. Nazarova

  Azo-derivative of phenylboronic acid as an active component of the membrane reversible to salicilate-anion

  Photoactive spatial proximity probes for binding pairs with epigenetic marks

  Andrei G. Kutateladze

  Tiffany Gustafson

  Tatiana G. Kutateladze

  Catherine Musselman

• 47

  Anna Yu. Gavrilova

  Nikolay V. Zyk

  Russian Journal of Organic Chemistry

  (4)

  608-610

  Lewis acids as co-reagents in sulfenylation reactions

  Ethers of sulfenic acids as sulfenilating agents

  Nikolay S. Zefirov

  Oxana B. Bondarenko

• 44

  Anna Yu. Gavrilova

  Nikolay V. Zyk

  Russ. Chem. Bull.

  . 2008

  2572-2578

  Ethers of sulfenic acids as sulfenilating agents

  Oxazolines as Dual Function Traceless Chromophores and Chiral Auxiliaries: Enantioselective Photoassisted Synthesis of Polyheterocyclic Ketones

  Andrei G. Kutateladze

  Oxazolines as Dual Function Traceless Chromophores and Chiral Auxiliaries: Enantioselective Photoassisted Synthesis of Polyheterocyclic Ketones

  Amino Azaxylylenes Photogenerated from o-Amido Imines: Photoassisted Access to Complex Spiro-Polyheterocycles

  Andrei G. Kutateladze

  Teresa Cowger

  Amino Azaxylylenes Photogenerated from o-Amido Imines: Photoassisted Access to Complex Spiro-Polyheterocycles

  Minimalist Relativistic Force Field: Prediction of Proton-Proton Coupling Constants in 1H NMR Spectra is Perfected with NBO Hybridization Parameters.

• Laboratory

  HPLC

  LC-MS

  Solid-phase synthesis

  Characterization

  GC-MS

  Organic Synthesis

  Mass Spectrometry

  Laboratory Skills

  Photochemistry

  Research

  Spectroscopy

  Catalysis

  UV/Vis

  Nuclear Magnetic Resonance (NMR)

  NMR

  Fluorescence

  Organic Chemistry

  Medicinal Chemistry

  Organometallic Chemistry

  Computationally driven reassignment of the structures of aldingenins A and B

  Andrei G. Kutateladze

  Michael T. Crimmins

  Hiroyuki Koshino

  Computationally driven reassignment of the structures of aldingenins A and B

  Photoassisted Synthesis of Enantiopure Alkaloid Mimics Possessing Unprecedented Polyheterocyclic Cores

  Andrei Kutateladze

  Photoassisted Synthesis of Enantiopure Alkaloid Mimics Possessing Unprecedented Polyheterocyclic Cores

  Halotrimethylsilanes as activating coreagents in sulfenylation reactions of olefins

  Nikolay S. Zefirov

  Oxana B. Bondarenko