McGill University - Engineering
Doctor of Philosophy (PhD)
The effect of thermal treatment on the physicochemical properties of minerals
Chemical Engineering
The University of Birmingham
Master of Science (MSc)
Instrumentation and Analytical Science
University of Manchester - Institute of Science and Technology
Chemical Engineering with German
University of Manchester - Institute of Science and Technology
Scanning Electron Microscopy
Science
Cell
Microsoft Office
Flotation
Nanotechnology
Characterization
Materials Science
Metallurgy
Powder X-ray Diffraction
Geology
Mineral Processing
Process Engineering
Chemical Engineering
Simulations
Nanomaterials
Physics
Minerals
Experimentation
Chemistry
Developing critical coalescence concentration curves for industrial process waters using dilution
James A. Finch
Developing critical coalescence concentration curves for industrial process waters using dilution
Richard Sheridan
Rare earth (RE) mineral deposits are typically processed using several different unit operations including flotation
gravity
magnetic and electrostatic separation techniques. Two of the most important beneficiation techniques for RE minerals are gravity and magnetic separation. Many RE minerals are found alongside low specific gravity gangue minerals thereby permitting the use of gravity separations to concentrate the heavy value RE minerals. Magnetic separation is used primarily to remove ferromagnetic gangue minerals as well as to separate individual paramagnetic rare earth minerals. \nThis work investigated the use of a wet high intensity magnetic separation (WHIMS) in conjunction with gravity pre-concentration steps (Knelson and Falcon centrifugal concentrators) to beneficiate a rare earth ore. The results of these separation steps are related to the magnetic properties of RE minerals
based on literature and measurements conducted using a vibrating sample magnetometer (VSM). \n
Processing a rare earth mineral deposit using gravity and magnetic separation
Surface Characterisation of Fergusonite
R. Gauvin
P. Chu
Mitra Mirnezami
A. Jordens
There is currently very little information on the physico–chemical properties of rare earth element bearing minerals
or on their processing. With the increasing demand for rare earths
this is something that needs to be addressed. This paper introduces some surface chemistry analysis of fergusonite (YNbO4)
and the bubble particle attachment. Zeta potential measurements indicate adsorption of sodium oleate and
to a lesser degree
potassium amyl xanthate onto the surface
and an increase in attachment to an air bubble is observed at pH 4?5 and 6?5. At a pH of 10?5
no attachment is observed
whether in the presence of the reagents or not. This analysis
although initial
will be used to initiate flotation tests
in order to facilitate the selective recovery of fergusonite. Two extensively characterised minerals
one hydrophilic (quartz) and one hydrophobic (galena) were also investigated as a comparison.
Surface Characterisation of Fergusonite
Olga Kuzmina
Bastnäsite is the chief valuable mineral in two of the world’s largest rare earth (RE) mineral deposits and is also found in a number of new RE deposits currently under development. This work used electrophoretic and electroacoustic zeta potential measurements to identify the interaction between bastnäsite and several different collectors. The results of these measurements were then compared with microflotation of bastnäsite and quartz
a common RE gangue mineral. Zeta potential measurements of bastnäsite determined the isoelectric point of bastnäsite to occur at approximately pH 6.3 (via electrophoretic measurement) and pH 8.1 (via electroacoustic measurement). Sodium oleate and Flotinor SM15 (a commercial phosphoric acid ester) are both shown to chemically adsorb onto the bastnäsite surface. Zeta potential measurements of bastnäsite with benzohydroxamic acid indicate significant adsorption
especially from pH 5 to pH 10. The microflotation results show that all three collectors were able to successfully recover bastnäsite. SM15 is the least selective collector as it floats both quartz and bastnäsite whereas benzohydroxamic acid is able to selectively float bastnäsite at pH 9. The recovery of bastnäsite using benzohydroxamic acid is also shown to be highly dependent on frother selection. The optimum pH of flotation for all three collectors occurs at pH 9.
Surface chemistry considerations in the flotation of bastnasite
Determining frother-like properties of process water in bitumen flotation
James A.Finch
Determining frother-like properties of process water in bitumen flotation
A review of the beneficiation of rare earth element bearing minerals
Y.P. Cheng
Rare earth elements (REEs) comprise the fifteen elements of the lanthanide series as well as yttrium
and may be found in over 250 different minerals. These elements are required for many different applications such as high-strength permanent magnets
catalysts for petroleum refining
metal and glass additives and phosphors used in electronic displays. The only REE bearing minerals that have been extracted on a commercial scale are bastnäsite
monazite
and xenotime. These minerals may be beneficiated using gravity
magnetic
electrostatic and flotation separation techniques. Increased demand for the different products manufactured from REE has resulted in a constriction of supply from China
which currently produces 97% of the world’s rare earths
via export quotas. Many new rare earth deposits are currently being developed to help meet the demand void created by the Chinese export quotas
however most of these developing deposits include rare earth minerals for which there is limited processing knowledge. This paper examines the separation techniques that are currently employed for rare earth mineral beneficiation and identifies areas in need of further research.
A review of the beneficiation of rare earth element bearing minerals
Conor Maloney
The need for fine grinding to liberate valuable minerals from low-grade ores has become a major concern due to the high energy requirements and\nlow energy efficiencies of comminution processes. One method being studied to improve efficiencies is microwave pre-treatment. Microwaves can\nselectively heat certain minerals (absorbers) within an ore
causing internal stresses and forming fractures along grain boundaries. Microwave pretreatment\nof an ore containing microwave-absorbing minerals and microwave-transparent gangue can significantly reduce grinding energy.\nHowever
these improvements must not be detrimental to downstream processing. This work investigated the effects of microwave radiation on the\ngrindability and flotability of a copper/nickel sulphide ore. A reduction in the Bond Work Index of 22%was observed after microwave pre-treatment\nin a 3.0kW multimodal microwave (2.45 GHz) for 60 s. Although a significant reduction in the required grinding energy was observed
the amount\nof energy required to treat the sample is significantly higher than the corresponding Bond Work Index reduction
indicating that the process remains\nsome distance from being economically viable. Microwave pre-treatment also showed beneficial effects on the flotation of the ore. Copper recovery\nremained constant while nickel recovery increased by 33.6% after 120 s of microwave exposure at 0.8 kW
and by 34.4% after a 30 s exposure at\n3.0 kW. Higher microwave exposure also showed an increase in concentrate grade and flotation kinetics of both copper and nickel.
Effect of microwave radiation on the processing of a Cu-Ni sulphide ore
Inverse gas chromatography has great potential in allowing an enhanced understanding of mineral surfaces
and the interactions between particles and air and water in mineral processing separations
such as flotation.\n\nTwo minerals of different degrees of natural hydrophobicity were investigated
namely galena and quartz. The surface energy was determined as a function of surface area
with the quartz sample displaying a higher work of adhesion
implying a higher degree of hydrophilicity. This was then compared to microflotation experiments. The higher work of adhesion to water for the quartz than galena (114.54 mJ m− 2 compared to 101.71 mJ m− 2 @ 5% coverage; 86.78 mJ m− 2 compared to 71.69 mJ m− 2 @ 38% coverage) was related to a lower recovery of quartz (6.94%) than galena (27.63%) through collectorless flotation.
Introducing inverse gas chromatography as a method of determining the surface heterogeneity of minerals for flotation
Olga Kuzmina
This paper investigated the physicochemical properties of allanite
a RE-silicate
by measuring zeta potential in the absence and presence of three different flotation collectors (benzohydroxamic acid
sodium oleate and dodecylamine). This data was then verified by microflotation experiments and with bubble-particle attachment pictures. The investigated properties of allanite were compared to those of quartz
a common gangue mineral in many RE deposits. The results of this work indicated that only dodecylamine was able to achieve a selective separation of allanite and quartz. This was accomplished by lowering the dodecylamine dosage so that only quartz was recovered by microflotation.
Physicochemical aspects of allanite flotation
Neil Rowson
James Finch
Raymond Langlois
Thomas Leadbeater
For the past 120 years
hydrocyclones have been used a wide variety of industrial applications
with their main use in mineral processing being as a classifier. Hydrocyclone characterization relies heavily on empirical and phenomenological models. There is a need to develop a method by which the flow patterns can be quantified under industrial conditions. Positron emission particle tracking (PEPT)
developed by the University of Birmingham in the late 1980s
has proven to be a powerful in situ visualization tool for engineering applications. This paper presents data on the motion of quartz particles in a two-inch hydrocyclone using the PEPT technique. Quartz tracer particles were labeled using the direct activation technique. The particle size range was between −2000 and +150 μm which illustrates the flow pattern of particles reporting to the underflow.
Particle flow visualization in quartz slurry inside a hydrocyclone using the positron emission particle tracking technique
Waters
Imperial College London
McGill University
Research work involved the separation of fine mineral particles through flotation using colloidal gas aphrons\n\nParticle tracking in a froth flotation cell using the positron emission particle tracking (PEPT) technique
Post Doctoral Research Associate
London
United Kingdom
Imperial College London
Associate Professor
Montreal
Canada Area
McGill University
My research involves mineral processing
specifically separation techniques. These include froth flotation
magnetic separation and gravity concentration.\n\nCurrent research work includes:\nProcessing rare earth bearing minerals\nDry processing of minerals\nRemoval of heavy metals from water\nModelling spiral concentrators
Assistant Professor
Montreal
Canada Area
McGill University