University of Mississippi - Chemistry
Doctor of Philosophy (Ph.D.)
Organic Chemistry
University of Illinois at Urbana-Champaign
Bachelor of Science (B.S.)
Chemistry
University of Kentucky
UV/Vis
Biochemistry
Microscopy
LC-MS
HPLC
Organic Synthesis
Chemistry
Chromatography
Medicinal Chemistry
Nuclear Magnetic Resonance (NMR)
Characterization
Mass Spectrometry
Science
NMR
Drug Discovery
Organic Chemistry
Nanotechnology
Spectroscopy
Protein Chemistry
Analytical Chemistry
Au137(SR)56 nanomolecules: composition
optical spectroscopy
electrochemistry and electrocatalytic reduction of CO2
Au137(SR)56
a nanomolecule with a precise number of metal atoms and ligands
was synthesized. The composition was confirmed by MALDI and ESI mass spectrometry using three unique ligands (–SCH2CH2Ph
–SC6H13
and –SC4H9) and nano-alloys with Ag and Pd. The electrocatalytic properties were tested for CO2 reduction.
Au137(SR)56 nanomolecules: composition
optical spectroscopy
electrochemistry and electrocatalytic reduction of CO2
Nathan Hammer
Strong electron-donating functionality is desirable for many organic donor-π-bridge-acceptor (D-π-A) dyes. Strategies for increasing the electron-donating strength of common nitrogen-based donors include planarization of nitrogen substituents and the use of low resonance-stabilized energy aromatic ring-substituted nitrogen atoms. Organic donor motifs based on the planar nitrogen containing heterocycle indolizine are synthesized and incorporated into dye-sensitized solar cell (DSC) sensitizers. Resonance active substitutions at several positions on indolizine in conjugation with the D-π-A π-system are examined computationally and experimentally. The indolizine-based donors are observed to contribute electron density with strengths greater than triarylamines and diarylamines
as evidenced by UV/Vis
IR absorptions
and oxidation potential measurements. Fluorescence lifetime studies in solution and on TiO2 yield insights in understanding the performance of indolizine-based dyes in DSC devices.
Indolizine-Based Donors as Organic Sensitizer Components for Dye-Sensitized Solar Cells
Delcamp
Georgia Institute of Technology
EPFL
University of Mississippi
University of Mississippi
Postdoctoral Scientist
EPFL
Postdoctoral Scientist
Georgia Institute of Technology