Texas A&M University College Station - Chemical Engineering
Postdoctoral Alexander von Humboldt Fellow
Chemistry
Max Planck Institute for Coal Research
Doctor of Philosophy (Ph.D.)
Chemical Engineering
University of Delaware
Bachelor of Science (B.S.)
Chemical Engineering
University of Florida
Chemical Engineering
Organic Chemistry
Research
Science
Engineering
Characterization
Nanotechnology
R
Catalysis
Nanomaterials
Materials Science
Process Simulation
Spectroscopy
Chemistry
Polymers
Supramolecular Assembly of Block Copolypeptide at Different Processing and Solution Conditions
Here we report the supramolecular assembly of poly( L-lysine)-b-polyglycine diblock copolypeptides at different solution conditions. Light scattering and confocal microscopy indicate that the supramolecular aggregates initially formed in solution are vesicles with a broad size distribution
depending strongly on the initial processing conditions. The vesicles formed after multiple pH cycles appear independent of the initial processing conditions and are related to the thermodynamic nature of the assembled supramolecular aggregates. Circular dichroism results verify that this change in size observed over pH cyclings tracks with the conformation changes of the lysine block confined in the vesicle membranes. This appears interesting for peptosome-based materials
implying a high level of fluidity in the membrane that allows the supramolecular aggregates formed in solution to respond to changes in pH. The results also show that the external stimulus
which is the change of pH in this study
provides an additional means to regulate polypeptide vesicle size and size distribution.
Supramolecular Assembly of Block Copolypeptide at Different Processing and Solution Conditions
Catalytic properties of dendron-OMS hybrids
The effect of surface modifications on protein microfiltration properties of Anopore (TM) membranes
Peptide Brush-Ordered Mesoporous Silica Nanocomposite Materials
The synthesis and characterization of melamine-based dendrimer/SBA-15-hybrids are reported. The current work demonstrates the ability to fabricate hybrid materials containing a high loading of organic moieties (30−35 wt %) that possess a well-defined structure. Numerous characterization methods including X-ray diffraction
electron microscopy
infrared spectroscopy
solid-state NMR spectroscopy
thermal gravimetric analysis
MALDI-MS
elemental analysis
and nitrogen porosimetry have been used to characterize the microstructure of the hybrids obtained.
Engineering Nanospaces: OMS/Dendrimer Hybrids Possessing Controllable Chemistry and Porosity
Shantz
Texas A&M University
SABIC
Tulane University
Houston
Texas
SABIC
Tulane University
New Orleans
Louisiana
Entergy Chair of Clean Energy Engineering
Department of Chemical and Biomolecular Engineering
Houston
Texas
Senior Manager
Corporate Research and Innovation
SABIC
Greater New Orleans Area
Interim Chair of Chemical and Biomolecular Engineering
Tulane University
Tulane University
Texas A&M University
College Station
Texas
2001 - 2006
Assistant Professor\n2006 - 2011
Associate Professor\n2011 - 2012
Nesbitt Professor of Chemical Engineering
Professor of Chemical Engineering